LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 ADHESIVE 81669 ADHESIVE 81669 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Item No.: ADHESIVE 81669 Part of Kit: 81669 Part No.: 81669 Product Name: Form-A-Thread(TM) Stripped Thread Repair Product Type: Adhesive 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Aromatic dimethacrylate ester 24448-20-2 35-40 Glass 65997-17-3 25-30 ALUMINUM 7429-90-5 20-25 ACRYLIC ACID* 79-10-7 3-5 Heterocyclic methacrylate 2455-24-5 1-3 SILICA, AMORPHOUS (FUMED) 7631-86-9 1-3 1-Acetyl-2-phenylhydrazine 114-83-0 0.1-1 CUMENE HYDROPEROXIDE* 80-15-9 0.1-1 2,6-DI-tert-BUTYL-p-CRESOL 128-37-0 0.1-0.5 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) ALUMINUM 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. ACRYLIC ACID 2 ppm TWA skin 10 ppm TWA skin 1 ppm TWA skin 5.9 mg/m3 skin 30 mg/m3 skin 3 ppm STEL skin SILICA, AMORPHOUS (FUMED) 10mg/m3 TWA 6mg/m3 TWA None 2,6-DI-tert-BUTYL-p-CRESOL None None 10 mg/m3 Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Liquid is an eye and skin irritant. Vapors may irritate eye, nose and throat. Estimated oral LD50 more than 5000 mg/kg. Estimated dermal LD50 more than 2000 mg/kg. Primary Routes of Entry: None known Signs and symptoms of Exposure: Irritation of eyes, skin , nose or throat. May LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Item No.: ADHESIVE 81669 3. HAZARDS IDENTIFICATION (continued) cause dermatitis on,prolonged contact in sensitive individuals. Existing Conditions Aggravated by Exposure: Acrylic acid: Upper respiratory and lung diseases, dermatitis Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Aromatic dimethacrylate ester ALG IRR NO NO NO Glass No Data NO NO NO ALUMINUM IRR LUN NO NO NO ACRYLIC ACID AC4 ALG COR IRR NO N/A NO Heterocyclic methacrylate ALG IRR NO NO NO SILICA, AMORPHOUS (FUMED) NUI NO N/A NO 1-Acetyl-2-phenylhydrazine ALG NO NO NO CUMENE HYDROPEROXIDE ALG CNS COR IRR MUT NO NO NO 2,6-DI-tert-BUTYL-p-CRESOL AC4 IRR MUT NO N/A NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc. ALG Allergen CNS Central nervous system COR Corrosive IRR Irritant LUN Lung MUT Mutagen NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: If ignited, burns with unusual heat evolution. In a fire, reaction with water is possible. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Item No.: ADHESIVE 81669 5. FIRE FIGHTING MEASURES (continued) Explosive Limits: (% by volume in air)Lower 2.0% Acrylic acid 30% Aluminum metal (% by volume in air)Upper 8.0% Acrylic acid Unknown Aluminum metal 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up with an inert absorbent. Store in a partly filled, closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. Avoid breathing of vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Grey Liquid Odor: Mild Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Low Specific Gravity 1.57 Volatile Organic Compound (EPA Method 24) 9.9% Vapor Pressure: Less than 5mm at 80°C Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: None Conditions to Avoid: Not available LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Item No.: ADHESIVE 81669 10. STABILITY AND REACTIVITY (continued) Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: No Prop65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Item No.: ADHESIVE 81669 16. OTHER INFORMATION (continued) NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0029 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 04 ACTIVATOR 81669 ACTIVATOR 81669 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Item No.: ACTIVATOR 81669 Part of Kit: 81669 Part No.: 81669 Product Name: Form-A-Thread(TM) Stripped Thread Repair Product Type: Activator 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Aromatic dimethacrylate ester 24448-20-2 40-45 Glass 65997-17-3 25-30 ALUMINUM 7429-90-5 20-25 Heterocyclic methacrylate 2455-24-5 1-3 SILICA, AMORPHOUS (FUMED) 7631-86-9 1-3 Organo-copper compound 1338-02-9 0.1-0.5 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) ALUMINUM 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. SILICA, AMORPHOUS (FUMED) 10mg/m3 TWA 6mg/m3 TWA None Organo-copper compound Cu 0.2mg/m3fume Cu 0.1mg/m3fume None Cu 1 mg/m3 dust Cu 1 mg/m3 dust Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Estimated oral LD50 more than 5000 mg/kg. Estimated dermal LD50 more than 2000 mg/kg. Primary Routes of Entry: None known Signs and symptoms of Exposure: May cause dermatitis on prolonged contact in sensitive individuals. Liquid may be an eye irritant Existing Conditions Aggravated by Exposure: None known LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 04 Item No.: ACTIVATOR 81669 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Aromatic dimethacrylate ester ALG IRR NO NO NO Glass No Data NO NO NO ALUMINUM IRR LUN NO NO NO Heterocyclic methacrylate ALG IRR NO NO NO SILICA, AMORPHOUS (FUMED) NUI NO N/A NO Organo-copper compound BLO IRR NO NO NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable ALG Allergen BLO Blood IRR Irritant LUN Lung NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Irritating organic vapors Unusual Fire or Explosion Hazards: If ignited, burns with unusual heat evolution. In a fire, reaction with water is possible. Explosive Limits: (% by volume in air)Lower 30% Aluminum metal (% by volume in air)Upper Unknown Aluminum metal 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up with an inert absorbent. Store in a partly filled, closed container until disposal. Residue LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 04 Item No.: ACTIVATOR 81669 6. ACCIDENTAL RELEASE MEASURES (continued) may be cleaned with solvent. 7. HANDLING AND STORAGE Safe Storage: Store below 110°F. Observe normal safety precautions. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Does not apply See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Blue-grey liquid Odor: Mild Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Low Specific Gravity 1.57 Volatile Organic Compound (EPA Method 24) 3.6% Vapor Pressure: Less than 5mm at 80°C Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 04 Item No.: ACTIVATOR 81669 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: No Prop65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 1 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 1 Reactivity Hazards: 1 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: January 22, 1996 Revision: 0024 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 REL.AGENT 81669 REL.AGENT 81669 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Item No.: REL.AGENT 81669 Part of Kit: 81669 Part No.: 81669 Product Name: Form-A-Thread(TM) Stripped Thread Repair Product Type: Release agent 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Light aliphatic solvent naphtha 64742-89-8 25-35 XYLENES* 1330-20-7 20-30 ISOBUTANE 75-28-5 10-20 PROPANE 74-98-6 5-10 ACETONE 67-64-1 3-10 Distillates (petroleum), hydrotreated light 64742-47-8 3-10 Poly(tetrafluoroethylene) 9002-84-0 3-10 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Light aliphatic solvent naphtha 5mg/m3 TWA mist 5mg/m3 TWA mist None XYLENES 100 ppm TWA 100 ppm TWA None 434 mg/m3 435 mg/m3 PROPANE Asphyxiant 1000 ppm None 1800 mg/m3 ACETONE 750 ppm TWA 750 ppm TWA None 1780 mg/m3 1800 mg/m3 Distillates (petroleum), hydrotreated light None None 200 ppm Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) Light aliphatic solvent naphtha 10 mg/m3 None XYLENES 150 ppm 150 ppm 651 mg/m3 655 mg/m3 ACETONE 1000 ppm 1000 ppm 2380 mg/m3 2400 mg/m3 LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Item No.: REL.AGENT 81669 3. HAZARDS IDENTIFICATION Toxicity: Eye, skin, and respiratory irritant. High vapor concentrations may cause dizziness or headache. Primary Routes of Entry: Skin and inhalation. Signs and symptoms of Exposure: Headache, nausea, dizziness. Narcosis at high concentrations. Skin dryness. Skin, eye, or respiratory irritation. Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Light aliphatic solvent naphtha No Data NO NO NO XYLENES AC4 CAR CNS IRR KID LIV NO NO NO ISOBUTANE CAR CNS LUN NO NO NO PROPANE CAR CNS IRR NO NO NO ACETONE BLO CNS IRR NO NO NO Distillates (petroleum), hydrotreated light No Data NO NO NO Poly(tetrafluoroethylene) No Data NO N/A NO ------------------------------------------------------------------------------- Abbreviations N/A Not Applicable AC4 ACGIH-Unclassifiable as human carc. BLO Blood CAR Cardiac CNS Central nervous system IRR Irritant KID Kidney LIV Liver LUN Lung 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Call a physician. Inhalation: Remove to fresh air if not breathing. Give mouth to mouth resuscitation, If breathing is difficult, give oxygen. Call a physician. Skin Contact: Wash with detergent and water. Eye Contact: Immediately flush with liberal amounts of water for at least 15 minutes. Obtain medical attention. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Item No.: REL.AGENT 81669 5. FIRE FIGHTING MEASURES Flash Point: Less than 77°F Method: Cleveland Open Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical, water fog. Hazardous Products formed by Fire or Thermal Decomp Hydrogen fluoride and carbonyl fluoride above 750°F Unusual Fire or Explosion Hazards: Aerosol cans may rupture in fires Explosive Limits: (% by volume in air)Lower Acetone: 2.5% Naphtha: 0.9% Xylene: 0.9% Propellant: 1.8% (% by volume in air)Upper Acetone: 12.8% Naphtha: 6.7% Xylene: 7% Propellant: 9.5% 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Eliminate all sources of ignition. Maintain adequate ventilation. Soak up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store in a cool dry area. Avoid high heat sources, opem flame and welding areas. Do not store near strong oxidants such as liquid chlorine, concentrated oxygen, permamganates or dichromates. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged breathing of vapor. Avoid eye and skin contact. Do not consume food, drink or tobacco in areas where they may be contaminated by this material. Wash hands well before eating or smoking. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or chemical goggles. Skin: Impervious rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. Local exhaust is preferrable. Mechanical exhaust is acceptable. See Section 2 for Exposure Limits. LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Item No.: REL.AGENT 81669 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Blue liquid Odor: Aliphatic Boiling Point: 160-180°F (Base) -43.7°F (Propellant) pH: Does not apply Solubility in Water: Insoluble Specific Gravity 0.84 at 70°F (Base) 0.5354 (Propellant) Volatile Organic Compound (EPA Method 24) Not available Vapor Pressure: Not available Vapor Density: More than 1.5 (Propellant) Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidants such as liquid chlorine concentrated oxygen, permanganates or dichromates. Conditions to Avoid: High temperatures or sources of ignition. Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. Do not incinerate cans still under pressure. EPA Hazardous Waste Number D001 - Hazardous waste per 40CFR 261.21 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity Hazard Class or Division: ORM-D Identification Number: None LOCTITE CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 EMERGENCY PHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Item No.: REL.AGENT 81669 14. TRANSPORTATION INFORMATION (continued) Marine Pollutant: None IATA Proper Shipping Name: Consumer Commodity Class or Division: Class 9 UN or ID Number: ID 8000 15. REGULATORY INFORMATION CA Proposition 65: No Prop65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 4 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 4 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0024