PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 05 Metal Repair Stik 82728 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Metal Repair Stik Item No.: 82728 Part of Kit: 21724 Product Type: Epoxy 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Epoxy resin 25068-38-6 10-40 Polymercaptan Proprietary 5-20 Substituted aminophenol 90-72-2 1-10 Benzyl alcohol 100-51-6 0.1-5 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: May cause irritation and sensitization to sensitive skin and mild irritation to eyes. May cause irritation if swallowed. Primary Routes of Entry: Skin contact Signs and symptoms of Exposure: Prolonged or repeated exposure may cause allergic sensitization. Existing Conditions Aggravated by Exposure: Dermatitis and skin allergy Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Epoxy resin ALG IRR NO NO NO Polymercaptan No Data NO NO NO Substituted aminophenol IRR NO NO NO Benzyl alcohol ALG COR IRR NO NO NO ------------------------------------------------------------------------------- PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 05 Product Name: Metal Repair Stik Item No.: 82728 3. HAZARDS IDENTIFICATION (continued) Abbreviations ALG Allergen COR Corrosive IRR Irritant 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attenion. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash thoroughly with soap and water. Eye Contact: Flush at least 15 minutes with clear water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 300°F Method: Tag Open Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Aldehydes; acids; oxides of carbon, sulfur, and nitrogen; ammonia; other unknown potentially toxic contaminants Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Avoid personal contact. Eliminate ignition skurces Ventilate area. Dike, contain and absorb with clay clay or other suitable material. (For large spills pump to storage/salvage vessels. Soak up with an inert absorbent such as clay, sand, or other suitable material anmd dispose of properly. FLush area with water to remove trace residue.) Prevent spill from entering drainage/sewer systems, waterways, and sufacr waters. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 05 Product Name: Metal Repair Stik Item No.: 82728 7. HANDLING AND STORAGE Safe Storage: Store in a cool, dry area away from high temperatures and flames. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid contact with skin, eyes,or clothing. Wash thoroughly with soap and water after using and particularly before eating, drinking, smoking, applying cosmetics, or using toilet facilities. Launder contaminated clothing and protective gear before reuse. Discard contaminated leather articles. Handle mixed resin and hardener in accordance with the potential hazard of the curing agent used. Provide appropriate ventilation/respiratory protection against decomposition products (see Section 10) during welding/flame cutting operations and particulates (silica) during sanding/grinding operations. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Polyethylene gloves. Ventilation: General mechanical is satisfactory. If odor is disagreeable, use local exhaust. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Resin: Grey putty; Hardener: Black putty Odor: Slight mercaptan Boiling Point: Not available pH: Does not apply Solubility in Water: Negligible Specific Gravity 1.9 Volatile Organic Compound (EPA Method 24) 1.25%; 23.8 grams per liter Vapor Pressure: Nil at 78°F Vapor Density: More than 1 Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizing agents. Conditions to Avoid: Exposure to open flames or excessive heat. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 05 Product Name: Metal Repair Stik Item No.: 82728 10. STABILITY AND REACTIVITY (continued) Hazardous Decomposition Products (non-thermal): Aldehydes; acids; oxides of carbon, sulfur amd nitrogen; other unknown and potentially toxic contaminants. 11. TOXICOLOGICAL INFORMATION Acure oral effects: LD50 more than 11.4 grams/mg (rat) Acure dermal effects: Slight irritant (rabbit) Eye irritation: Slight irritant (rabbit) 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: No California Proposition 65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 05 Product Name: Metal Repair Stik Item No.: 82728 16. OTHER INFORMATION (continued) Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: November 13, 1996 Revision: 0004 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 06 Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste 82730 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82730 Part of Kit: 21724 Product Type: Epoxy 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % RESIN Epoxy resin 25068-38-6 40-45 Calcium carbonate 471-34-1 30-40 Barium sulfate 7727-43-7 10-15 SILICA, AMORPHOUS, precipitated 112926-00-8 1-5 TITANIUM DIOXIDE 13463-67-7 1-5 HARDENER Calcium carbonate 1317-65-3 30-45 Polymercaptan Proprietary 30-35 Barium sulfate 7727-43-7 10-15 Iron oxide 1309-38-2 10-15 DIETHYLENETRIAMINE 111-40-0 5-10 Heptakis(dipropyleneglycol)- triphosphate 13474-96-9 1-5 PHENOL, 4,4'-ISOPROPYLIDENEDI-* 80-05-7 1-5 SILICA, AMORPHOUS, precipitated 112926-00-8 1-3 * This component is listed as a SARA Section 313 Toxic Chemical. Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) RESIN Calcium carbonate 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 respir. Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None 5 mg/m3 respir. SILICA, AMORPHOUS, precipitated 10 mg/m3 TWA 6 mg/m3 TWA None TITANIUM DIOXIDE 10 mg/m3 dust 15 mg/m3 dust None 5 mg/m3 resp HARDENER Calcium carbonate 10 mg/m3 TWA 15 mg/m3 dust None dust 5 mg/m3 respir. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82730 2. COMPOSITION, INFORMATION ON INGREDIENTS (continued) Barium sulfate 10 mg/m3 dust 10 mg/m3 dust None 5 mg/m3 respir. Iron oxide 5 mg/M3 (Fe) 10 mg/M3 (Fe) None particulate DIETHYLENETRIAMINE 1 ppm skin 1 ppm TWA None 4.2mg/m3 skin 4mg/m3 PHENOL, 4,4'-ISOPROPYLIDENEDI- None None 10 mg/m3 SILICA, AMORPHOUS, precipitated 10 mg/m3 TWA 6 mg/m3 TWA None Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) RESIN HARDENER 3. HAZARDS IDENTIFICATION Toxicity: Eye and skin irritant. May irritate upper respiratory tract. May cause skin burns and corneal injury resulting in permanent impairment of vision including blindness. May cause sensitization of skin and respiratory tract. Ingestion may cause burns of mouth and throat. Primary Routes of Entry: Ingestion, skin, inhalation Signs and symptoms of Exposure: Eye or skin irritation or injury. Allergic responses such as sensitization or dermatitis. Existing Conditions Aggravated by Exposure: None known Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA RESIN Epoxy resin ALG IRR NO NO NO Calcium carbonate NUI NO NO NO Barium sulfate LUN NO NO NO SILICA, AMORPHOUS, precipitated NUI NO NO NO TITANIUM DIOXIDE AC4 IRR NUI NO NO NO HARDENER Calcium carbonate NUI NO NO NO Polymercaptan No Data NO NO NO Barium sulfate LUN NO NO NO Iron oxide No Data NO NO NO DIETHYLENETRIAMINE ALG IRR NO NO NO Heptakis(dipropyleneglycol)- PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82730 3. HAZARDS IDENTIFICATION (continued) triphosphate No Data NO NO NO PHENOL, 4,4'-ISOPROPYLIDENEDI- ALG IRR NO NO NO SILICA, AMORPHOUS, precipitated NUI NO NO NO ------------------------------------------------------------------------------- Abbreviations AC4 ACGIH-Unclassifiable as human carc. ALG Allergen IRR Irritant LUN Lung NUI Nuisance dust 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Does not apply Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Before use, amine vapors may be evolved at high temperatures; oxides of carbon; unidentified organic compounds. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Scrape up material and store in closed container until disposal. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82730 7. HANDLING AND STORAGE Safe Storage: Store in a cool, dry area. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin contact. Keep away from eyes. Do not breath vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Sufficient to maintain vapor concentration below TLV. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Resin: Black; Hardener: Beige Odor: Resin: Mild; Hardener: Moderate Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Insoluble Specific Gravity Resin: 1.80; Hardener: 1.81 Volatile Organic Compound (EPA Method 24) Resin: 4.94%; 889 grams per liter Hardener: 0%; 0 grams per liter Vapor Pressure: Not available Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizers, acids, chlorinated hydrocarbons. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 05 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82730 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number D005 - May be a TCLP waste per 40CFR 261.24/Barium 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Consumer Commodity (Not more than four liters); Corrosive liquids, basic, organic, n.o.s. (Contains diethylenetriamine) (More than four liters) Hazard Class or Division: ORM-D (Not more than four liters); Class 8, Packing Group III (More than four liters) Identification Number: None (Not more than four liters); UN 3267 (More than four liters) Marine Pollutant: None IATA Proper Shipping Name: Corrosive liquids, basic, organic, n.o.s. (Contains diethylenetriamine) Class or Division: Class 8, Packing Group III UN or ID Number: UN 3267 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Epichlorohydrin 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2 Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 06 of 06 Product Name: Rapid Metal(TM) Fast Cure Steel-Filled Epoxy Paste Item No.: 82730 16. OTHER INFORMATION (continued) Prepared By: Jean Tobbe Title: Environmental Health & Safety Specialist Company: Loctite Corp., 1001 Tr Br Cr, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: April 15, 1997 Revision: 0006 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 04 PERMASTEX POXY POUCH RESIN RESIN 82725 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Product Name: PERMASTEX POXY POUCH RESIN Item No.: RESIN 82725 Part of Kit: 21724 Product Type: Epoxy adhesive 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Epoxy resin 26142-30-3 10-15 Epoxy resin 25068-38-6 3-85 Epoxy resin 28906-96-9 3-5 Epoxy resin 25085-99-8 0-80 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Possible skin and eye irritant.May cause skin or eye injury. Possible sensitizer. Primary Routes of Entry: None known Signs and symptoms of Exposure: May cause dermatitis or sensitization on prolonged contact. Heated vapors may cause headache, nausea, dizziness, or respiratory irritation. Existing Conditions Aggravated by Exposure: Allergy, eczema, skin conditions. Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Epoxy resin ALG IRR NO NO NO Epoxy resin ALG IRR NO NO NO Epoxy resin No Data NO NO NO Epoxy resin ALG IRR NO NO NO ------------------------------------------------------------------------------- PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 04 Product Name: PERMASTEX POXY POUCH RESIN Item No.: RESIN 82725 3. HAZARDS IDENTIFICATION (continued) Abbreviations ALG Allergen IRR Irritant 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at leat 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Phenolics, oxides of carbon, hydrogen chloride, aldehydes Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Soak up with an inert absorbent. Store in a closed container until disposal. 7. HANDLING AND STORAGE Safe Storage: Store below 100°F (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid prolonged skin contact. Keep away from eyes. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Not normally necessary, but mechanical and local PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 04 Product Name: PERMASTEX POXY POUCH RESIN Item No.: RESIN 82725 8. EXPOSURE CONTROLS, PERSONAL PROTECTION (continued) exhaust ventilation may be desirable for prolonged use in a confined area. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Clear water white to amber liquid Odor: Mild Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.13-1.17 Volatile Organic Compound (EPA Method 24) 0.765%; 8.64 - 8.95 grams per liter Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Oxidizing agents, bases, acids, amines, mercaptans Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 04 Product Name: PERMASTEX POXY POUCH RESIN Item No.: RESIN 82725 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: Warning: This product contains a chemical known to the State of California to cause cancer. Teaces of epichlorohydrin 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 1 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 1* Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Health and Safety Company: Loctite Corporation 1001 Trout Brook Crossing, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: February 26, 1997 Revision: 0002 PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 01 of 04 HARDENER 82725 HARDENER 82725 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Item No.: HARDENER 82725 Part of Kit: 21724 Product Type: Epoxy hardener 2. COMPOSITION, INFORMATION ON INGREDIENTS Ingredients CAS No. % Polymercaptan Proprietary 80-85 Substituted aminophenol 90-72-2 5-10 Nonylphenol 25154-52-3 3-5 Heptakis(dipropyleneglycol)- triphosphate 13474-96-9 1-3 Ingredients which have exposure limits Exposure Limits (TWA) ACGIH OSHA OTHER Ingredients (TLV) (PEL) Exposure Limits (STEL) ACGIH OSHA Ingredients (TLV) (PEL) 3. HAZARDS IDENTIFICATION Toxicity: Skin and eye irritant. Possible respiratory irritant. The aminophenol can cause severe irritation and may be corrosive on prolonged contact. It may be a sensitizer. It can also be corrosive to eye tissue leading to permanent injury including blindness. It may irritate the respiratory tract and may cause delayed lung damage upon overexposure to fumes or vapors. It can also cause fatigue, muscular weakness, labored breathing, or gastrointestinal irritation if swallowed. The relatively low concentration of the aminophenol in the product may minimize some or all of these effects. Primary Routes of Entry: Skin, ingestion, inhalation. Signs and symptoms of Exposure: Eye, skin, respiratory, or gastrointestinal irritation. It is possible that such irritation may be severe and lead to burns. Allergic reactions may occur. Existing Conditions Aggravated by Exposure: Skin, eye, lung conditions. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 02 of 04 Item No.: HARDENER 82725 3. HAZARDS IDENTIFICATION (continued) Literature Referenced Carcinogen Ingredients Target Organ and Other Health Effects NTP IARC OSHA Polymercaptan No Data NO NO NO Substituted aminophenol IRR NO NO NO Nonylphenol ALG COR IRR NO NO NO Heptakis(dipropyleneglycol)- triphosphate No Data NO NO NO ------------------------------------------------------------------------------- Abbreviations ALG Allergen COR Corrosive IRR Irritant 4. FIRST AID MEASURES Ingestion: Do not induce vomiting. Keep individual calm. Obtain medical attention. Inhalation: Remove to fresh air. If symptoms persist, obtain medical attention. Skin Contact: Wash with soap and water. Eye Contact: Flush at least 15 minutes with water. Obtain medical attention. 5. FIRE FIGHTING MEASURES Flash Point: More than 200°F Method: Tag Closed Cup Recommended Extinguishing Agents: Carbon dioxide, foam, dry chemical Hazardous Products formed by Fire or Thermal Decomp Oxides of carbon, sulfur, and phosphorus, hydrogen sulfide, phosphite/phosphate esters, hydrocarbon fragments. Unusual Fire or Explosion Hazards: None Explosive Limits: (% by volume in air)Lower Not available (% by volume in air)Upper Not available 6. ACCIDENTAL RELEASE MEASURES Steps to be taken in case of spill or leak: Take up with an inert absorbent. Store in a closed container until disposal. PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 03 of 04 Item No.: HARDENER 82725 7. HANDLING AND STORAGE Safe Storage: Store below 110°F. (Contact Loctite Customer Service 1-800-243-4874 for shelf Life information) Handling: Avoid skin contact. Keep away from eyes. Do not breathe vapors. 8. EXPOSURE CONTROLS, PERSONAL PROTECTION Eyes: Safety glasses or goggles. Skin: Rubber or plastic gloves. Ventilation: Local exhaust ventilation should be provided. See Section 2 for Exposure Limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance: Colorless, viscous liquid. Odor: Unpleasant Boiling Point: More than 300°F pH: Does not apply Solubility in Water: Slight Specific Gravity 1.08 Volatile Organic Compound (EPA Method 24) 11.08%; 119.7 grams per liter Vapor Pressure: Less than 5mm at 80°F Vapor Density: Not available Evaporation Rate (Ether = 1) Not available 10. STABILITY AND REACTIVITY Stability: Stable Hazardous Polymerization: Will not occur Incompatibility: Strong oxidizing agents, epoxy/amine mixtures. Possibly acids, peroxides, acetaldehyde, caustics. Conditions to Avoid: Not available Hazardous Decomposition Products (non-thermal): None 11. TOXICOLOGICAL INFORMATION See Section 3. 12. ECOLOGICAL INFORMATION No data available PERMATEX INDUSTRIAL CORPORATION 07/02/97 ROCKY HILL, CONNECTICUT 06067 TELEPHONE: (860) 571-5100 MATERIAL SAFETY DATA SHEET Page 04 of 04 Item No.: HARDENER 82725 13. DISPOSAL CONSIDERATIONS Recommended methods of disposal: Incinerate following EPA and local regulations. EPA Hazardous Waste Number NH - Not a RCRA Hazardous Waste Material 14. TRANSPORTATION INFORMATION DOT (49 CFR 172) Domestic Ground Transport Proper Shipping Name: Unrestricted Hazard Class or Division: Unrestricted Identification Number: None Marine Pollutant: None IATA Proper Shipping Name: Unrestricted Class or Division: Unrestricted UN or ID Number: None 15. REGULATORY INFORMATION CA Proposition 65: No Californis Proposition 65 chemicals are known to be present. 16. OTHER INFORMATION Estimated NFPA(R) Code: Health Hazard: 2 Fire Hazard: 1 Reactivity Hazard: 0 Specific Hazard: Does not apply Estimated HMIS(R) Code: Health Hazard: 2* Flammability Hazard: 1 Reactivity Hazards: 0 Personal Protection: See Section 8. NFPA is a registered trademark of the National Fire Protection Assn. HMIS is a registered trademark of the National Paint and Coatings Assn. Prepared By: Stephen Repetto Title: Research Chemist, Environmental Health & Safety Company: Loctite Corporation 1001 Trout Brook Crossing, Rocky Hill CT 06067 (24hr.) Phone: (860) 571-5100 Revision Date: February 26, 1997 Revision: First Issue